Syntheses of syndiotactic poly(methyl methacrylate)s with Grignard reagents (RMgBr).
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چکیده
منابع مشابه
Di-Grignard reagents and metallacycles
Aliphatic ,w-dibromides can be converted to the corresponding c,w-di—Grignard reagents; for those members carrying less than four carbon atoms between the functions, special procedures are required. The synthesis, structure and applications of the di-Grignard reagents are discussed; particular emphasis is placed on the structures of the corresponding cyclic dialkylmagnesiums, and on the use of ...
متن کاملThermal epimerization of diastereomeric Grignard reagents.
Thermal epimerization is the key to changing the endo-to-exo ratio of the diastereomeric bornyl and fenchyl Grignard reagents from 67:33 to 96:4 and from 20:80 to 80:20, respectively.
متن کاملEnantioselective Addition of Grignard Reagents to Aldehydes
The addition of Grignard reagents to aldehydes in the presence of chiral aminoalcohols shows a moderate enantioselectivity. The study carried out with a series of ligands allows the correlation between the structural characteristics and their reactivity. Introduction The use of chiral aminoalcohol to lead asymmetrically nucleophilic additions of organometallics to carbonyl compounds is a field ...
متن کاملIron-catalyzed alkylations of aromatic grignard reagents.
Significance: The development of iron-catalyzed cross-coupling reactions is an extremely promising field of research, taken into account the importance of this method for current organic synthesis and the multiple problems connected with commonly used Pdand Ni-catalyzed processes. The group of Cahiez reported the first iron-catalyzed alkyl–aryl cross-coupling reaction, suitable for industrial l...
متن کاملStereocontrolled Syntheses of Piperidine Derivatives Using Diastereoselective Reactions of Chiral 1,3-Oxazolidines with Grignard Reagents: Asymmetric Syntheses of the Pinidine Enantiomers.
Pinidine is the main constituent of Pinus sabiniana and related plant species as determined, along with its chemical structure, by Tallent and co-workers over 40 years ag0.1 The complete stereochemistry of pinidine was unambiguously established by Hill to be la, usmg chemical and spectroscopic methods.2 Very recently, further work on the pinidine alkaloid contents of pine (Pinus) and spruce (Pi...
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ژورنال
عنوان ژورنال: KOBUNSHI RONBUNSHU
سال: 1986
ISSN: 0386-2186,1881-5685
DOI: 10.1295/koron.43.435